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In this paper, we describe the synthesis, structural characterization, redox behavior, and cytotoxic activity towards a panel of human tumor cell lines of six Pt(IV) complexes with the racemic DACHEX ligand: cis,trans,cis-[Pt(OXA)(OH)(DACHEX)] (1), cis,trans,cis-[Pt(OXA)(AcO)(DACHEX)] (AcO = acetate) (2), cis,trans,cis-[Pt(OXA)(BzO)(DACHEX)] (BzO = benzoate) (3), cis,trans,cis-[Pt(OXA)Cl(DACHEX)] (4), cis,trans,cis-[Pt(OXA)(AcO)Cl(DACHEX)] (5), and cis,trans,cis-[Pt(OXA)(OH)Cl(DACHEX)] (6). 2.
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